ANDREX - RRS James Cook in Falklands

ANDREX - CTD recovery

ANDREX - Weddell Gyre Iceberg

ANDREX - South Georgia Penguins

ANDREX - RRS James Cook in Weddell Gyre

ANDREX - CFC sampling

ANDREX - RRS James Cook in South Georgia

Oxygen and nutrients

The main ANDREX nutrients webpage can be found here. Nutrients are defined as elements used in the production of organic matter during photosynthesis in the upper ocean. Whilst the term nutrients has also been applied to trace chemicals such as iron, in this case focus is on the 'traditional' elements of nitrate, phosphate and silicate.

These constitents are removed from the surface layers of the ocean by living organisms as they incorporate them into cells, tissues and extracellular structures, with oxygen generated as a by-product. This biogenic material can then decompose (this time consuming oxygen see below), returning the nutrients to the water column (see Redfield equation below).

Redfield equation

The different rates at which these processes occur can affect the distribution of these chemicals in the world's water masses e.g. the slow remineralisation of silica skeletons as compared to soft tissue (predominated by nitrogen and silica) leads to an enrichment of silicate in older waters. Ths facet can lead to silica being used a tracer of ocean circulation.

 

Oxygen & Nutrients in ANDREX study area
Concentration of nitrate, silicate and oxygen at different depth levels in the ANDREX study area. CLICK TO ENLARGE. From GLODAP - Key et al., (2004)
For N and Si, low concentrations are at the surface as P > R & D. Below this, R & D predominate so levels are higher. In the deep, the influence of lower nutrient North Atlantic water can be seen moving southwards in the lower latitudes. O2 gives information on the ventilation age of a water mass. Highest levels are therefore at the surface, with relative maxima in deep waters, indicative of their more recent formation.

On ANDREX, nutrients and oxygen were analysed by a team from NOC, with oxygen investigated by Winkler titration, and nutrients using an autoanalyser - this mixes chemical reagents with seawater sample aliquots causing the nitrate, phosphate and silicate present to under a colour change. The magniude of this reaction is then detected and quantified using spectrophotmetry. For a more detailed description of this process and the instrumentation involved, see the ANDREX@NOC nutrients webpage.

ANDREX - Oxygen & Nutrients Lab on RRS James Cook
Laboratory used on RRS James Cook during ANDREX-1 for oxygen and nutrients analysis. Autoanalyser is in centre. Sample cuvettes used for seawaetr sample collection are in foreground.

REFERENCE:
Key, R. M., A. Kozyr, C. L. Sabine, K. Lee, R. Wanninkhof, J. L. Bullister, R. A. Feely, F. J. Millero, C. Mordy, and T.-H. Peng (2004), A global ocean carbon climatology: Results from Global Data Analysis Project (GLODAP), Global Biogeochem. Cycles, 18, GB4031, doi:10.1029/2004GB002247

School of Environmental Sciences, University of East Anglia, Norwich NR4 7TJ, UK
Photos by Pete Brown and Karel Castro Morales
Last updated 19 November 2009. Site maintained by Pete Brown

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