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G. Richard Stephenson
Refereed Publications and Patents:
2005:
127. K.I. Booker-Milburn, M.R. Kimberley, R. Gillan, K. Ichinose, G.R. Stephenson, Y. Ebizuka, D.A. Hopwood,
Enantioselective reduction of b-keto-acids using engineered Streptomyces coelicolor A3(2).
Angew. Chem. Int. Ed. Engl., (2005) 44, 1121-1125.
2004:
127. S. Schouteeten, J.P. Tranchier, F. Rose-Munch, E. Rose, A. Aufrant, G.R. Stephenson, Cationic (h6-arene)tricarbonylmanganese linked to neutral (h6-arene)tricarbonylchromium complexes.
Organometallics, (2004) 23, 4308-4316.
126. B. Jacques, J.P. Tranchier, F. Rose-Munch, E. Rose, G.R. Stephenson and C. Guyard-Duhayon,
Cationic (h6-arene)tricarbonylmanganese linked to ferrocene complexes.
Organometallics, (2004) 23, 184-193.
125. T. Taguchi, K. Kunieda, M. Takeda-Shitaka, D. Takaya, N. Kawano, M.R. Kimberley, K.I. Booker-Milburn, G.R. Stephenson, H. Umeyama, Y. Ebizuka, K. Ichinose,
Remarkably different structures and reaction mechanisms of ketoreductases for the opposite stereochemical control in the biosynthesis of BIQ antibiotics.
Bioorganic and Medicinal Chemistry, (2004) 12, 5917-5927.
2003:
124. M. Ozawa, T. Taguchi, T. Itoh, Y. Ebizuka, K.I. Booker-Milburn, G.R. Stephenson, K. Ichinose, Structure and biosynthetic implication of (S)-NHAB, a novel shunt product from a disruptant of the actVI-ORFA gene for actinorhodin biosynthesis in
Streptomyces coelicolor A3(2),
Tetrahedron, (2003), 59, 8793-8798.
123. C.E. Anson, T.J. Baldwin, N.J. Clayden, C.S. Creaser, O. Egyed, M.A. Fey, W.E., Hutchinson, A. Kavanaugh, G.R. Stephenson, P.J Walker,
Silica-mounted FTIR-active organometalcarbonyl derivatives as functional materials,
Journal of Optoelectronics and Advanced Materials, (2003), 5, 533-554.
122. C.E. Anson, C.S. Creaser, A.V. MALKOV, L. Mojovic, G.R. Stephenson, Flavonoid derivatives as organometallic bioprobes.
J. Organomet. Chem., (2003), 668, 101.
2002:
121. C.S. Creaser, W.E. Hutchinson, G.R. Stephenson, An attenuated total reflectance optrode sensor incorporating infrared-active carbonylmetal probe groups.
Sensors and Actuators, (2002), 82B, 150.
2001:
120. M.F.N.N. Carvalho, M.A.N.D.A. Lemos, L.F. Veiros, G.R. Stephenson, Mechanism of the electrochemical reduction of [Fe(h5-C6H7)(CO)3][PF6] - a theoretical approach to the intermediates.
J. Organomet. Chem., (2001), 632, 49.
119. J.-P. Tranchier, R. Chavignon, D. Prim, A. Aufrant, J. Giner-Planas, F. Rose-Munch, E. Rose, G.R. Stephenson,
Organochromium/organoiron dipoles comprising (h6-arene)chromium and (h5-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers.
Tetrahedron Lett., (2001), 42, 3311-3313.
118. R.D.A. Hudson, C.E. Anson, M.F. Mahon, G.R. Stephenson, Regio- and stereoselectivity in long-range asymmetric induction controlled by carbonyliron groups: Crystal structures of dicarbonyl-L-[(1,2,3,4,5-h)-1-R-4-methoxycyclohexadienyl]iron(1+) hexafluorophosphate(1-) [(R = isopropenyl, L = CO), (R = 1-styryl, L = CO), (R = 1-prop-1-enyl, L = PPh3)] and two of their neutral malonate adducts.
J. Organomet. Chem., (2001), 630, 88-103.
117. C.S. Creaser,W.E. Hutchinson, G.R. Stephenson, FTIR sensing of inhomogeneous systems using immobilized organometalcarbonyl probe groups.
The Analyst, (2001), 126, 647-651.
116. C.E. Anson, R.D.A. Hudson, D.G. Smyth, G.R. Stephenson, Reactivity patterns in cationic tricarbonyliron complexes: Crystallographic
proof of stereoselectivity in long range asymmetric control in the 1,3/1,2'
series.
Appl. Organomet. Chem., (2001), 15, 16-22.
2000:
115. C.S. Creaser, W.E. Hutchinson, G.R. Stephenson, Molecular sensing
via an immobilized organometalcarbonyl probe.
Applied Spectroscopy, (2000), 54,
1624-1628.
114. C.E. Anson, G. Dave, G.R. Stephenson, Stereocontrolled preparation
of stereocomplementary regioisomeric tricarbonyliron complexes in enantiopure
form.
Tetrahedron, (2000), 56, 2273-2281.
113. T. Taguchi, K. Ituo, Y. Ebizuka, F. Malpartida, D.A. Hopwood, C.M. Surti,
K.I. Booker-Milburn, G.R. Stephenson, K. Ichinose, Chemical
Characterisation of disruptants of the Steptomyces coelicolor A3 actVI genes
involved in actinorhodin biosynthesis.
J. Antibiotics, (2000), 53, 144-152.
112. C.E. Anson, S. Hartmann, R.D. Kelsey, G.R. Stephenson, X-ray
crystallographic proof of regioselectivity in a nitrosobenzene cycloaddition,
and development of a novel in situ heterocycloaddition trap for use during
decomplexation of tricarbonyliron diene complexes in hippeastrine synthesis.
Polyhedron, (2000), 19, 569-571.
111. C.E. Anson, M.J. Bibb, K.I. Booker-Milburn, C. Clissold, P.J. Haley,
D.A. Hopwood, K. Ichinose, W.P. Revill, G.R. Stephenson, C.M. Surti,
Genetic engineering of Streptomyces coelicolor A3(2) for the enantioselective
reduction of unnatural b-keto-ester substrates.
Angew. Chem. Int. Ed. Engl.,
(2000), 39, 224-227.
1999:
110. MALKOV, A.V., AUFFRANT, A., RENARD, C., ROSE, E., ROSE-MUNCH, F. OWEN,
D.A., SANDOE, E.J., & STEPHENSON, G.R. Addition of aryl substituents to
cyclohexadienyliron electrophiles in the development of routes to C12 central
building blocks for alkaloid synthesis.
Inorg. Chim. Acta, (1999), 296,
139-149.
109. MALKOV, A.V., MOJOVIC, L., STEPHENSON, G.R. TURNER, A.T., & CREASER,
C.S. Attachment of IR-active organometallic probe groups to flavonoid inducers
of nod gene expression. J. Organometal. Chem., (1999), 589, 103-110.
108. ICHINOSE, K., SURTI, C., TAGUCHI, T., MALPARTIDA, F., BOOKER-MILBURN,
K.I., STEPHENSON, G.R., EBIZUKA, Y. & HOPWOOD, D.A. Proof that the actVI
genetic region of Streptomyces coelicolor A3(2) is involved in stereospecific
pyran ring formation in the biosynthesis of actinorhodin. Bioorg. Med. Chem.
Lett., (1999), 9, 395-400.
1998:
107. BACH, N.J., BAKER, S.R., GILMORE, J., LEWTHWAITE, R.A., MCKILLOP, A.,
SAWYER, J.S., STEPHENSON, G.R., & URQUHART, M.W.J. Process for preparing
N-benzyl indoles. United States Patent, (1998), 5,807,866.
106. ANSON, C.E., CREASER, C.S., DOWNIE, J.A., EGYED, O., MALKOV, A.V.,
MOJOVIC, L., STEPHENSON, G.R., TURNER, A.T., & WILSON, K.E. Organometallic
flavonoid derivatives as spectroscopic probes. Bioorg. Med. Chem. Lett., (1998),
8, 3549-3554.
105. ANSON, C.E., HUDSON, R.D.A., OSBORNE, S.A., SMYTHE, D.G., &
STEPHENSON, G.R. h4 to h5: Stereocontolled reactivation of exocyclic triene
iron complexes. Tetrahedron Lett., (1998), 39, 7603-7606.
1997:
104. ROSE-MUNCH, F., SUSANNE, C., BALSSA, F., ROSE, E., VAISSERMAN, J., LICANDRO, E., PAPAGNI, A., MAIORANA, S., MENG, W.-D., & STEPHENSON, G.R.
Nucleophile addition of chromium and tungsten carbene anions to cationic
organotricarbonylmetal complexes. J. Organometal. Chem., (1997), 545-546,
9-16.
103. ANSON, C.E., CREASER, C.S., EGYED, O., & STEPHENSON, G.R. FTIR studies
of organometalcarbonyl-tagged enzymes. Spectrochim. Acta, (1997), 53,
1867-1877.
102. BACH, N.J., BAKER, S.R., GILMORE, J., LEWTHWAITE, R.A., MCKILLOP, A.,
SAWYER, S., STEPHENSON, G.R., & URQUHART, M.W.J. Process for preparing
N-benzyl indoles. European Patent Application, (1997), 96308306.8.
101. ICHINOSE, K., SURTI, C., HOPWOOD, D.A., MALPARTIDA, F., BOOKER-MILBURN,
K.I., & STEPHENSON, G.R. Stereochemical control involved in the
biosynthesis of benzochromanequinone antibiotics in Streptomyces spp. Tennen
Yuki Kagobutsu Toronkai Koen Yoshishu, (1997), 38, 505-510 [CA (1997) 125,
3224276].
100. HENDRICKX, E., PERSOONS, A., SAMSON, S., & STEPHENSON, G.R. Nonlinear
optical properties in bimetallic monocation complexes of iron. J. Organomet.
Chem., (1997), 542, 295-297.
99. HUDSON, R.S.A. OSBORNE, S.A., & STEPHENSON, G.R. Ester functionalised
alkene-extended cyclohexadienyl complexes. Tetrahedron, (1997), 53,
4095-4104.
98. VAN DEN BEUKEN, E., SAMSON, S., SANDOE, E.J. & STEPHENSON, G.R.
Alkynylcyclohexadienyl tricarbonyliron complexes: a new directing effect for
organoiron-mediated synthesis J. Organometal. Chem., (1997), 530, 251-253.
97. ANSON, C.E., ATTWOOD, M.R., RAYNHAM, T.M., SMYTH, D.G., & STEPHENSON,
G.R. More efficient iterative uses of tricarbonyliron complexes are possible by
diastereoselective formation of h5-cyclohexadienyl complexes. Tetrahedron
Lett., (1997), 38, 505-508.
1996:
96. HUDSON, R.D.A. OSBORNE, S.A., & STEPHENSON, G.R. Long-range asymmetric
induction by conjugate addition to alkenylcyclohexadienyliron complexes
Tetrahedon Lett., (1996), 37, 9009-9012.
95. SVENSSON, M., REES, G.D., ROBINSON, B.H., & STEPHENSON, G.R.
Phosholipid-stabilised water-in-oil microemulsions: a study of ester synthesis
by Humicola lanuginosa lipase. Colloids and Surfaces B: Interfaces, (1996), 8,
101-111.
94. HUDSON, R.D.A., OSBORNE, S., & STEPHENSON, G.R. Reactions of a new
Sorensen-type nucleophile with organoiron complexes: synthesis of
N-deprotected, diastereomerically pure amino acids. Synlett, (1996),
845-846.
93. SANDOE, E.J., STEPHENSON, G.R., & SWANSON, S. Regiochemical switching
with aryl-substituted cyclohexadienyliron complexes in a formal total synthesis
of lycoramine. Tetrahedron Lett., (1996), 37, 6283-6286.
92. HOWELL, J.A.S., BELL, A.G., O'LEARY, P.J., STEPHENSON, G.R., HASTINGS, M,
HOWARD, P.W., OWEN, D.A., WHITHEAD, A.J., MCARDLE, P., & CUNNINGHAM, D.
Synthesis and reactivity of cyclic and acyclic
(1-(acyloxy)pentadienyl)Fe(CO)2LX and (1-alkoxypentadienyl)Fe(CO)2LX salts
(L=CO, PPh3). Organometallics, (1996), 15, 4247-4257.
91. ANSON, C.E., CREASER, C.S., & STEPHENSON, G.R. FTIR study of p-stacking
effects in (h6-arene)tricarbonylchromium complexes: application as a molecular
sensor for aromatic analytes. Spectrochim. Acta, (1996), 52, 1183-1191.
90. CARVALHO, M.F.N.N., POMBEIRO, A.J.L., SHROPSHIRE, I.M., & STEPHENSON,
G.R. Electrochemical behaviour and reactivity of cyclohexadienyliron complexes.
Inorg. Chim. Acta, (1996), 248, 45-49.
89. ATTWOOD, M.R., RAYNHAM, T.M., SMYTH, D.G., & STEPHENSON, G.R.
Elaboration of a trifloxycyclohexadieneiron p-complex by palladium-catalysed
coupling. Tetrahedron Lett., (1996), 37, 2731-2734.
88. ANSON, C.E., BALDWIN, T.J., CREASER, C.S., FEY, M.A., & STEPHENSON,
G.R. IR-active Organometallic pH Probes. Organometallics, (1996), 15,
1451-1456.
87. BACH, N.J., BAKER, S.R., GILMORE, J., LEWTHWAITE, R.A., MCKILLOP, A.,
SAWYER, S., STEPHENSON, G.R., & URQUHART, M.W.J. Process for preparing
N-benzyl indoles. U.K. Patent Application, (1996) 9523948.9.
1995:
86. REES, G.D., ROBINSON, B.H., & STEPHENSON, G.R. Preparative-scale
kinetic resolutions catalysed by microbial lipases immobilised in
AOT-stabilised microemulsion-based organogels: cryoenzymology as a tool for
improving enantioselectivity. Biochim. Biophys. Acta, (1995), 1259, 73-81.
85. CROOKS, G.E., REES, G.D., ROBINSON, B.H., SVENSSON, M., & STEPHENSON,
G.R. Comparison of hydrolysis and esterification behavior of Humicola
lanuginosa and Rhizomucor miehei lipases in AOT-stabilised water-in-oil
microemulsions: II - Effect of temperature on reaction kinetics and general
considerations of stability and productivity. Biotechnol. Bioeng., (1995), 48,
190-196.
84. CROOKS, G.E., REES, G.D., ROBINSON, B.H., SVENSSON, M., & STEPHENSON,
G.R. Comparison of hydrolysis and esterification behavior of Humicola
lanuginosa and Rhizomucor miehei lipases in AOT-stabilised water-in-oil
microemulsions: I - Effect of pH and water content on reaction kinetics.
Biotechnol. Bioeng., (1995), 48, 78-88.
83. REES, G.D., ROBINSON, B.H., & STEPHENSON, G.R. Macrocyclic lactone
synthesis by lipases in water-in-oil microemulsions. Biochim. Biophys. Acta,
(1995), 1257, 239-248.
82. BALAZS, M. and STEPHENSON, G.R., Regiocontrol switching in C-C bond
formation during decomplexation of a tricarbonyl(h4-cyclohexadiene)iron
complex. J. Organometal. Chem., (1995), 498, C17-C19.
81. MCKILLOP, A., STEPHENSON, G.R. & TINKL, M. A Facile iron-mediated entry
to the 2,3,3a,7a-tetrahydroindole nucleus. Synlett, (1995), 669-670.
80. MALKOV, A.V., & STEPHENSON, G.R. Anomolous deprotonation reaction of
tricarbonyl(h5-1-arylcyclohexadienyl)iron complexes. J. Organometal. Chem.,
(1995), 489, C74-C77.
79. MALKOV, A.V. & STEPHENSON, G.R. Fine-tuning electrophilicity of
cationic tricarbonyliron complexes. J. Organometal. Chem., (1995), 489,
C44-C47.
78. BREEN, C., BROOKS, J.S., FORDER, S., MAGGS, A.A., MARSHALL, G., &
STEPHENSON, G.R. Organometallic cation-exchanged phyllosilicates: 57Fe
Mossbauer spectroscopic study of organoiron complexes on a low-iron
montmorillonite. J. Materials Chem., (1995), 5, 97-104.
1994:
77. CALISKAN, O.A., ANIL, H, & STEPHENSON, G.R. Cephalaria saponin A, a new
bidesmosidic triterpene saponin from Cephalaria transsylvanica. J. Nat. Prod.,
(1994), 57, 1001-1003.
76. ANSON, C.E., CREASER, C.S., & STEPHENSON, G.R. [(h6-Benzocrown
ether)Cr(CO)3] complexes as FTIR-readable molecular sensors for alkali metal
cations. J. Chem. Soc., Chem. Commun., (1994), 2175-2176.
75. STEPHENSON, G.R. & HOWARD, P.W. Circular dichroism spectra of
tricarbonyliron complexes. J. Chem. Soc., Perkin Trans. 1, (1994),
2873-2880.
74. GENET, J.P., HUDSON, R.D.A., MENG, W.-D., ROBERTS, E., STEPHENSON, G.R.,
& THOIMBERT, S. Schiff base nucleophiles: progress towards the general
application of organoiron complexes in amino acid synthesis. Synlett, (1994),
631-634.
73. STEPHENSON, G.R. & MILNE, K. Evaluation of phosphoramide derivatives of
carboxylic acid esters for the alkylation of tricarbonyliron complexes with
weak directing groups. (Transition metal mediated asymmetric synthesis, part
16). Aust. J. Chem., (1994), 47, 1605-1612.
72. HOWELL, J.A.S., BELL, A.G., O'LEARY, P.J., MCARDLE, P., CUNNINGHAM, D.,
STEPHENSON, G.R., & HASTINGS, M. Access to homochiral acyclic
(diene)Fe(CO)3 complexes containing electron donor substitutents.
Organometallics, (1994), 13, 1806-1812.
71. CREASER, C.S., FEY, M.A., & STEPHENSON, G.R. Environment sensitivity of
FTIR-active metal carbonyl probe groups. Spectrochimica Acta, (1994), 50A,
1295-1299.
70. ANSON, C.E., CREASER, C.S., EGYED, O., FEY, M.A., & STEPHENSON, G.R.
FTIR detection of an enzyme-bound organometalcarbonyl probe in the presence of
the unbound probe molecule. J. Chem. Soc., Chem. Commun., (1994), 39-40.
1993:
69. ASTLEY, S.T. & STEPHENSON, G.R. Preparation and reactivity of cuprate
derivatives of lithium 6-lithiopiperonylate with
tricarbonyl(2-methoxycyclohexadienyl)iron(1+) hexafluorophoshpate. J. Chem.
Soc., Perkin Trans. 1, (1993), 1953-1955.
68. MCKILLOP, A., STEPHENSON, G.R., & TINKL, M. Leaving group placement to
control the stereoselective organo-iron-based synthesis of regioisomeric
tetrahydrophenanthridine derivatives. J. Chem. Soc., Perkin Trans. 1, (1993),
1827-1828.
67. STEPHENSON, G.R., FINCH, H. OWEN, D.A., & SWANSON, S. Transition metal
mediated asymmetric synthesis, Part 15. Directing group competition in
organoiron intermediates in the synthesis of (±)-O-methyljoubertiamine.
Tetrahedron, (1993), 49, 5649-5662.
66. ALEXANDER, I.J., HALES, N.J., & STEPHENSON, G.R. Transition metal
mediated asymmetric synthesis, Part XIV. A new strategy for the reactivation of
tricarbonyliron complexes. J. Organometal. Chem., (1993), 453, 111-115.
65. ASTLEY, S.T., MEYER, M., & STEPHENSON, G.R. Hippeastrine synthesis: A
combined biodioxygenation/organoiron chirality relay approach. Tetrahedron
Lett., (1993), 34, 2035-2038.
64. REES, G.D., JENTA, T.R.J., NASCIMENTO, M.G, CATAURO, M., ROBINSON, B.H.R.,
STEPHENSON, G.R., & OLPHERT, R.D.G. Use of water-in oil microemulsions and
geletin-containing microemulsion-based gels for lipase-catalysed ester
synthesis in organic solvents. Ind. J. Chem., (1993), 32B, 30-34.
1992:
63. DUNN, M.J., JACKSON, R.F.W., & STEPHENSON, G.R. Reactions of a
serine-derived zinc/copper reagent with tricarbonyl(cyclohexadienyl)iron salts:
synthesis of protected amino acids. Synlett, (1992), 905-906.
62. STEPHENSON, G.R. & ASTLEY S.T. Hippeastrine synthesis: Functionalised
metallated arenes in an organoiron route to a tricyclic model. Synlett, (1992),
507-509.
61. CREASER, C.S. & STEPHENSON, G.R. Spectroscopic investigations using
organometallic compounds. U.K. Patent Application, (1992), 9209856.5, 7
May.
60. STEPHENSON, G.R., THOMAS, R.D. & CASSIDY, F. An organoiron approach to
the synthesis of dihydrodioscorine. Synlett, (1992), 247-248.
59. CREASER, C.S., KOUPAI-ABYAZANI, M.R. & STEPHENSON, G.R. Gas
chromatographic-mass spectrometric characterisation of flavanones in citrus and
grape juices. The Analyst, (1992), 117, 1105-1109.
58. KOUPIA-ABYAZANI, M.R., CREASER, C.S., & STEPHENSON, G.R. Separation and
identification of flavone, flavonol, isoflavone and flavanone aglycones by
capillary column gas chromatography. Phytochem. Anal., (1992), 3, 80-84.
57. STEPHENSON, G.R., OWEN, D.A., FINCH, F. & SWANSON, S. The role of the
substituent pattern in determining selectivity in the preparation of
tricarbonyl(h5-cyclohexadienyl)iron(1+) salts by acid-catalysed
demethoxylation. Aust. J. Chem., (1992), 45, 121-134.
1991:
56. STEPHENSON, G.R., HOWARD, P.W. & TAYLOR S.C. Regioselective access to
tricarbonyliron complexes: controlled preparation and reactions of
trifluoromethyl-substituted complexes. J. Organomet. Chem., (1991), 419,
C14-C17.
55. CREASER, C.S. & STEPHENSON, G.R. Spectroscopic investigations using
organometallic compounds. U.K. Patent Application, (1991), 9110017.2, 9
May.
54. CREASER, C.S., KOUPAI-ABYAZANI, M.R. & STEPHENSON, G.R. Origin and
control of multi-peak formation in the analysis of trimethylsilyl derivatives
of flavanone aglycones in capillary column gas chromatography. J.
Chromatography, (1991), 586, 323-328.
53. STEPHENSON, G.R., VOYLE, M. & WILLIAMS, S. A route to acyclic
tricarbonyl(h5-trienyl)iron(1+) complexes for use in polyene asymmetric
synthesis. Tetrahedron Lett., (1991), 32, 5265-5268.
52. STEPHENSON, G.R., PALOTAI, I.M., ROSS, W.D. & TUPPER, D.E. An
organometallic approach for the synthesis of lycorine: substituent tolerance in
the arylation step. Synlett, (1991), 586-588.
51. STEPHENSON, G.R., HOWARD, P.W., OWEN, D.A. & WHITEHEAD, A.J.
Complementary regioselection in nucleophile additions to cationic
h5-cyclohexadienyl iron complexes. J. Chem. Soc., Chem. Commun., (1991),
641-642.
50. STEPHENSON, G.R., OWEN, D.A., FINCH, H. & SWANSON, S. Organometallic
equivalents of cyclohexenone di-cation synthons for the total synthesis of
O-methyljoubertiamine. (Transition metal mediated asymmetric synthesis, part
13). Tetrahedron Lett., (1991), 32, 1291-4.
49. STEPHENSON, G.R., THOMAS, R.D. & CASSIDY, F. Transition metal mediated
asymmetric synthesis XII. Tricarbonyliron complexes as intermediates to
isoquinuclidines. J. Organomet. Chem., (1991), 402, C59-C62.
48. CREASER, C.S., KOUPAI-ABYAZANI, M.R. & STEPHENSON, G.R. Mass spectra of
trimethylsilyl derivatives of naturally occurring flavonoid aglycones and
chalcones. Org. Mass Spectrometry, (1991), 26, 157-160.
47. STEPHENSON, G.R., HOWARD, P.W. & TAYLOR, S.C. Assignment of absolute
configurations from the circular dichroism spectra of cyclic h4-diene complexes
of Fe(CO)3. J. Chem. Soc., Chem. Commun., (1991), 127-9.
1990:
46. OWEN, D.A., STEPHENSON, G.R., FINCH, H. & SWANSON, S. Phenyl directing
groups in the demethoxylation route to tricarbonyl(h5-cyclohexadienyl)iron(1+)
complexes. J. Organomet. Chem., (1990), 395, C5-C8.
45. HOWARD, P.W., STEPHENSON, G.R. & TAYLOR, S.C. Evidence for an anomalous
microbial oxidation of acetophenone: new access to optically active
tricarbonyliron complexes. J. Chem. Soc., Chem. Commun., (1990), 1182-4.
44. OWEN, D.A., STEPHENSON, G.R., FINCH, H., & SWANSON, S. Aryl-substituted
cyclohexadienyl complexes: novel intermediates for an organometallic approach
to Sceletium and Amaryllidaceae alkaloid synthesis. Tetrahedron Lett., (1990),
31, 3401-4.
43. STEPHENSON, G.R., VOYLE, M. & WILLIAMS, S. Electrophilic vinylogous
dienyl p-complexes: a novel approach to the stereocontrolled preparation of
polyenes. Tetrahedron Lett., (1990), 31, 3979-82.
1989:
42. HASTINGS, M. & STEPHENSON, G.R. Model studies for an organometallic
route to cis,trans dienols. J. Organomet. Chem., (1989), 375, C27-C30.
41. PIPER, M.R.J., STEPHENSON, G.R., TAYLOR, R.J.K., BREEN, C., BROOKS, J.S.
& WILLIAMS, G.L. Charge distribution in bimetallic organometallic cations.
J. Chem. Soc., Chem. Commun., (1989), 1798-1800.
40. CREASER, C.S., KOUPAI-ABYAZANI, M.R. & STEPHENSON, G.R. Capillary
column gas chromatography of methyl and trimethylsilyl derivatives of some
naturally occurring flavonoid aglycones and other phenolics. J. Chromatography,
(1989), 478, 415-421.
39. MENG, W.D. & STEPHENSON, G.R. Driven equilibria: a strategy for the
regioconvergent preparation of tricarbonyl(h5-cyclohexadienyl)iron(1+)
complexes by hydride abstraction. J. Organomet. Chem., (1989), 371,
355-360.
38. OWEN, D.A., STEPHENSON, G.R., FINCH, H. & SWANSON, S. Transition metal
mediated asymmetric synthesis, Part 11: 2-Aryl substitutents: new directing
groups in cyclohexadienyl p-complexes. Tetrahedron Lett., (1989), 30,
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37. HOWARD, P.W., STEPHENSON, G.R. & TAYLOR S.C. Transition metal mediated
asymmetric synthesis X. Homochiral p-complexes with planar chirality: synthetic
equivalents of chiral cyclohexadiene dications. J. Organomet. Chem., (1989),
370, 97-109.
36. PALOTAI, I.M., STEPHENSON, G.R., ROSS, W.J. & TUPPER, D.E. First
alkylation of a 1-methoxy substituted tricarbonyl-(h5-cyclohexadienyl)iron(1+)
complex. J. Organomet. Chem., (1989), 364, C11-C14.
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35. HOWARD, P.W., STEPHENSON, G.R. & TAYLOR, S.C. Convenient access to
homochiral tricarbonyliron complexes. J. Chem. Soc., Chem. Commun., (1988),
1603-1604. (Transition metal mediated asymmetric synthesis, Part 9).
34. RANDALL, G.P., STEPHENSON, G.R. & CHRYSTAL, E.J.T. Transition metal
mediated asymmetric synthesis VIII. Preparation of
tricarbonyl(cyclohexadienyl)iron(1+) cations with oxygenated side-chains. J.
Organomet. Chem., (1988), 353, C47-C50.
33. HOWARD, P.W., STEPHENSON, G.R. & TAYLOR, S.C. Transition metal mediated
asymmetric synthesis VII. 6-Methoxycyclohexadienyl complexes: Access to
synthetic equivalents of cyclohexadiene dications. J. Organomet. Chem., (1988)
339, C5-C8.
32. ALEXANDER, R.P., MORLEY, C. & STEPHENSON, G.R. Transition metal
mediated asymmetric synthesis. Part 6. Organometallic approaches to the
enantiomer synthesis of tridachione: a role for planar chirality in synthesis
design. J. Chem. Soc., Perkin Trans. 1, (1988), 2069-2074.
1987:
31. PALOTAI, I.M., STEPHENSON, G.R. & KANE-MAGUIRE, L.A.P. Planar chirality
in organometallic complexes: applications in organic enantiomer synthesis. J.
Organomet. Chem., (1987), 319, C5-10.
30. ALEXANDER, R.P., JAMES, T.D. & STEPHENSON, G.R. Alkylation of
tricarbonyliron complexes by trimethylsilyl cyanide: synthetic and kinetic
studies. J. Chem. Soc., Dalton Trans., (1987), 2013-2016.
29. ALEXANDER, R.P. & STEPHENSON, G.R. Transition-metal mediated asymmetric
synthesis. Part 5. Alternative Methods for the formation of
tricarbonyl(h5-cyclohexadienyl)iron(1+) salts. J. Chem. Soc., Dalton Trans.,
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1986:
28. CASY, G., FURBER, M., RICHARDSON, K.A., STEPHENSON, G.R. & TAYLOR,
R.J.K. Alkylation reactions of propargyl alcohol; improved routes to
prostaglandin a-side-chain precursors. Tetrahedron, (1986), 42, 5849-5856.
27. ALEXANDER, R.P. & STEPHENSON, G.R. Reversal of regiocontrol in the
alkylation of an arene p-complex. J. Organomet. Chem., (1986), 314, C73-75.
26. ALEXANDER, R.P. & STEPHENSON, G.R. A superior method for the addition
of cyanide to substituted tricarbonyl(h5-cyclohexadienyl)iron(1+) salts. J.
Organomet. Chem., (1986), 299, C1-C3.
1985:
25. STEPHENSON, G.R. An organometallic route to tetrahydrocarbazolones. J.
Organomet. Chem., (1985), 286, C41-C43.
24. CURTIS, H., JOHNSON, B.F.G. & STEPHENSON, G.R. Studies on the
regioselective preparation of tricarbonyl(cyclohexadienyl)iron(1+) salts. J.
Chem. Soc., Dalton Trans., (1985), 1723-5.
1984:
23. ATTON, J.G., EVENS, D.J., KANE-MAGUIRE, L.A.P. & STEPHENSON, G.R.
Resolution of [Fe(CO)3(1-5-h-dienyl]+ cations and assignment of absolute
configuration by circular dichroism spectroscopy. J. Chem. Soc., Chem. Commun.,
(1984), 1246-8.v
22. BIRCH, A.J., RAVERTY, W.D. & STEPHENSON, G.R. Chirality transfer in the
coordination sphere of iron. Organometallics, (1984), 3, 1075-1079.v
21. HARLAND, L., STEPHENSON, G.R. & WHITTAKER, M.J. Barriers to Fe(CO)3
rotation in substituted cyclohexadienyl complexes. J. Organomet. Chem., (1984),
263, C30-C32.
1982:
20. STEPHENSON, G.R. Transition-metal mediated asymmetric synthesis. IV.
Chelation of malonate esters by a chiral lanthanide shift reagent: a general
method to measure the enantiomeric excess of
tricarbonyl(cyclohexadienyl)iron(1+) salts. Aust. J. Chem., (1982), 35,
1939-1943.
19. ATTON, J.G., KANE-MAGUIRE, L.A.P., WILLIAMS, P.A. & STEPHENSON, G.R.
Chiral discrimination in organometallic systems. Reaction of
[Fe(CO)3(1-5h-2-MeOC6H6)]+ with (R)-(+)589-1-phenylethylamine.
J. Organomet. Chem., (1982), 232, C5-C8.
18. STEPHENSON, G.R. Transition-metal mediated asymmetric synthesis. Part 3.
Preparation and stereospecific alkylation of unsymmetrically substituted
tricarbonyl(cyclohexadienyl)iron(1+) salts: An organometallic approach to the
synthesis of carvone, cryptomerion and bilobanone. J. Chem. Soc., Perkin Trans.
1, (1982) 2449-2456.
17. BIRCH, A.J., LIEPA, A.J. & STEPHENSON, G.R. Organometallic complexes in
synthesis. Part 16. Reaction of tricarbonyl(cyclohexadienyl)iron(1+) salts with
aromatic amines. J. Chem. Soc., Perkin Trans. 1, (1982) 713-717.
1981:
16. STEPHENSON, G.R. Transition metal mediated asymmetric synthesis. II
Complete resolution of (2R,5S)-
(-)-tricarbonyl[1-5-h-(2-methoxy-5-methylcyclohexadienyl)]iron(1+)
hexafluorophosphate(1-) by selective crystallization of enantiomers. Aust. J.
Chem., (1981), 34, 2339-2345.
15. BIRCH, A.J., RAVERTY, W.D. & STEPHENSON, G.R. Organometallic complexes
in organic synthesis. 15. The absolute configuration of some simply substituted
tricarbonyliron complexes. J. Org. Chem., (1981), 46, 5166-5172.
14. BIRCH, A.J. & STEPHENSON, G.R. Regioselectivity of nucleophilic
additions to tricarbonyl(h5-methyl-2,4-cyclohexadien-1-yl)iron(1+)PF6-:
Temperature dependence of hydride reductions. J. Organomet. Chem., (1981), 218,
91-104.
13. BIRCH, A.J. & STEPHENSON, G.R. Optically active
tricarbonyl(cyclohexadienyl)iron(1+) salts: Synthetic equivalents to spatially
directed organic cations. Tetrahedron Lett., (1981), 22, 779-782. (Transition
metal mediated asymmetric synthesis, Part 1).
12. BIRCH, A.J., BANDARA, B.M.R., CHAMBERLAIN, K., CHAUNCY, B., DAHLER, P.,
DAY, A.I., JENKINS, I.D., KELLY, L.F., KHOR, T.-C., KRETSCHMER, G., LIEPA,
A.J., NARULA, A.S., RAVERTY, W.D., RIZZARDO, E., SELL, C., STEPHENSON, G.R.,
THOMPSON, D.J. & WILLIAMSON, D.H. Organometallic compounds in organic
synthesis - XI. The strategy of lateral control of reactivity:
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equivalents. Tetrahedron, Supplement 9, (1981), 37, 289-302.
11. JOHNSON, B.F.G., LEWIS, J., PARKER, D.G. & STEPHENSON, G.R. Synthetic
studies with iron carbonyl complexes. Reaction of carbon nucleophiles with
tricarbonyl(cyclohexadienyl)iron tetrafluoroborate: addition of the anion of
nitromethane to the dienyl cation. J. Organomet. Chem., (1981), 204,
221-228.
1980:
10. BIRCH, A.J., DAHLER, P, NARULA, A.S. & STEPHENSON, G.R.
Tricarbonyl(cyclohexadienyl)iron complexes: synthetic equivalents of aryl
cations; a facile synthesis of 2-aryl-cyclopentenones and its application
towards prostaglandin analogues. Tetrahedron Lett., (1980), 21, 3817-3820.
9. JOHNSON, B.F.G., LEWIS, J., PARKER, D.G. & STEPHENSON, G.R. Synthetic
studies with iron carbonyl complexes. Fragmentation of b-alcoholic
tricarbonyl(diene)iron(0) complexes in the mass spectrometer; use to
distinguish positional isomers. J. Organomet. Chem., (1980), 197, 77-84.
8. JOHNSON, B.F.G., LEWIS, J., PARKER, D.G. & STEPHENSON, G.R. Synthetic
studies with iron carbonyl complexes. Versatile synthesis of olefinic
side-chains to a tricarbonyl(cyclohexadiene)iron(0) ring. J. Organomet. Chem.,
(1980), 197, 67-75.
7. JOHNSON, B.F.G., LEWIS, J., PARKER, D.G. & STEPHENSON, G.R. Synthetic
studies with iron carbonyl complexes. Protonation and acetylation of
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6. BIRCH, A.J., RAVERTY, W.D. & STEPHENSON, G.R. Absolute configuration of
some tricarbonyl(cyclohexadiene)iron complexes. J. Chem. Soc., Chem. Commun.,
(1980) 857-859.
5. JOHNSON, B.F.G., LEWIS, J. & STEPHENSON, G.R. Protonation and
acetylation of tricarbonyl(5-exo-(isopropenyl)cyclohexa-1,3-diene)iron.
Regiospecific formation of tricarbonyl(1-(substituted)- cyclohexadienylium)iron
cations. Tetrahedron Lett., (1980), 21, 1995-1996.
4. BIRCH, A.J., NARULA, A.S., DAHLER, P., STEPHENSON, G.R. & KELLY, L.F.
Organometallic compounds in organic synthesis: reactions of some
tricarbonyl(cyclohexadienylium)iron complexes with
1,2-bis(trimethylsiloxy)-1-cyclopentene. A novel route to
2-(substituted)-2-cyclopenten-1-ones. Tetrahedron Lett., (1980), 21,
979-982.
3. BIRCH, A.J., RAVERTY, W.D. & STEPHENSON, G.R. Asymmetric synthesis of
optically active tricarbonyliron complexes of 1,3-dienes. Tetrahedron Lett.,
(1980), 21, 197-200.
1979:
2. BIRCH, A.J., LIEPA, A.J. & STEPHENSON, G.R. Organometallic compounds in
organic synthesis. Some tricarbonyl(cyclohexadienyl)iron cations and nitrogen
containing nucleophiles. Tetrahedron Lett., (1979), 20, 3565-3568.
1978:
1. JOHNSON, B.F.G., LEWIS, J, STEPHENSON, G.R. & VICHI, E.J.S. Preparation
and reactions of triphenylphosphine and triphenylphosphite complexes of
(benzylideneacetone)dicarbonyliron(0). J. Chem. Soc., Dalton Trans., (1978),
369-373.
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